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Wednesday, August 8, 2012

How Calendered Vinyl Films are Made

By Jim Hingst @hingst_jim

This story explains the various steps in manufacturing calendered vinyl films: blending, fluxing, milling, calendering, embossing...


I usually compare the calendering  process to rolling out pie dough. In reality, the manufacturing process is a little more complex than that. In the calendering process, PVC material is squeezed between gigantic, heated, polished-steel rollers that form the vinyl into a very thin sheet of film.

A modern calendering line is also more expensive than grandma’s rolling pin, with capital equipment investments ranging typically from $10 million to $15 million. In addition, the calendering rolls alone cost several hundreds of thousands of dollars.

The production lines at companies, such as Achilles, feature advanced computer controls, which allowed continuous monitoring and in-process adjustments of machine functions.

In addition to focusing on the raw materials that create calendered vinyl, I’ll review the calendering process’s basic steps: blending, fluxing, milling, calendering, embossing, cooling and winding.

Raw materials.

PVC resin is the key ingredient. However, by itself, it’s a very hard and brittle plastic material. Additives — plasticizers, stabilizers, lubricants, pigments and processing aids — change the film’s physical properties and make it easier to process. 

PVC resin, pigments and additives comprising the “dry blend” are combined with the liquid plasticizer in a giant mixer. Photo courtesy of Achilles USA, Inc.

Plasticizers, which are liquids incorporated into the formulation, soften the hard PVC resin and make the films more flexible.

Plasticizers in polymeric calendered vinyls are more complex than those in monomeric films. Monomeric plasticizer comprises linear (sometimes branched) molecular chains, whereas polymeric plasticizer features complex branched chains of a higher molecular weight. The weightier polymeric molecules resist migration and create a more stable and longer-life plastic.

Plasticizers add flexibility to the final film. Plasticizer additions soften the film’s feel, or “hand.” Normal vinyl films used in graphics applications contain between 20% and 25% plasticizer. The higher-molecular-weight, polymeric-plasticized mixes have a higher viscosity (rheology) than monomeric systems, and are processed at slower production speeds. These plasticizers are more expensive than the monomerics, and are less efficient, which means they require a higher content of a more expensive material manufactured at lower speeds. 

The plasticizer’s molecular weight helps determine its stability. Higher-molecular-weight, polymeric plasticizer comprises very big, bulky, slow-moving molecules. Hence, they stay in the film.

The early, lower-molecular-weight monomeric plasticizer molecules were more mobile. They moved around easily and readily migrated out of the PVC into other adjoining materials, such as the adhesive coated on the film. Modern monomeric plasticizers are less mobile, which limits migration into the adhesive.    

Heat and UV light prematurely age products, especially vinyl. As the film ages, it yellows and degrades. Films can lose their elasticity and become brittle. Heat and UV stabilizers slow down this aging process. Although monomeric vinyl formulations don’t usually contain UV absorbers, they’re often incorporated into the vinyl (and adhesive) — for overlaminating applications — to impart some UV protection to the digital image or photograph being protected.

Lubricants assist the film’s release from the hot calender rolls during production and act as internal processing aides during production. They not only prevent PVC film from sticking to the rollers, they also improve the compound’s process.

Pigmentation is achieved via inorganic and organic pigments, which are usually first ground into the plasticizer to achieve a specified particle size (for full-color development). The pigment selection will depend upon the vinyl’s end application.

Economical inorganic pigments provide higher opacity than organics. High-performance calendered vinyls use the same pigment opportunities as the more expensive cast products.

The Calendering Process.


By itself, the PVC resin is as hard and brittle as a saltine cracker. Thus, to transform the PVC resin into a flexible plastic, it must be compounded with other vinyl-film ingredients. 


The dry blend and plasticizer are combined in a giant mixer. Imagine the margaritas that you could make in blender like this? Photo courtesy of Achilles USA, Inc.

Once all the raw materials are weighed and blended, into a very fine powder with the consistency of cake flour, the blend is fed into the extruder’s screw — the machine’s fluxing section. Under heat and pressure, the extruder continues the mixing process, evenly dispersing all the additives with the PVC resin. In the fluxing or plastification process, all the separate ingredients fuse together into one homogenous mass of plastic called the “melt.” As the fine powder melts, at  approximately 300°F,  the extruder kneads the material into a hot, twisted plastic rope. The extruder also helps strain out any foreign particles, which could damage the machinery. 

In the extruder the ingredients are heated and fused together in what is called the plastification process. Photo courtesy of Achilles USA, Inc.


Next, the hot, plastic rope is fed into a two-roll mill bin and rolled into a rough sheet of film. In the manufacturing process, the heat is continually increased, making the film more malleable so it can be rolled increasingly thinner. During this milling process, edge trim can be reworked into the mix.

In the two-roll mill the hot plastic rope is squeezed into a thick, rough sheet of plastic. Photo courtesy of Achilles USA, Inc.

After the two-roll mill, the material passes a metal detector. This inspection step prevents any metal from reaching the calendering rolls.  Even the tiniest metallic speck could cause irreparable damage and necessitate roller replacement.

Calender Rolls.


The calender comprises four, rather heavy, highly polished, 2-ft.-diameter steel rolls. Calendering rolls can be arranged into various configurations, such as “L,” “F” (or inverted “L”) and “Z”. The plant I visited utilized a four-roll “L” configuration.

The thick sheet of plastic is fed into the top of the calendering stack. Photo courtesy of Achilles USA, Inc.


During the calendering process, the heat increases, and the vinyl sheet passes between the rollers. During this process, the film is squeezed into a much thinner and wider sheet.

The calender rolls subject the vinyl sheet to thousands of pounds of pressure per square inch. Such intense forces and rapid production speeds can bend and deflect these massive rolls.

To compensate for  the rolls’ deflection, some complex mechanical-engineering ideas have been incorporated into modern machinery, including crowned rolls (which are thicker in the middle than on the edges) and rolls that are crossed slightly to one another, rather than perfectly parallel, and designed to counter the rolls’ bending by applying pressure in the counter-direction.

In the calendering stack the plastic film is squeezed into a much thinner and wider sheet. Photo courtesy of Achilles USA, Inc.
These measures ensure an optimum profile so the vinyl’s caliper remains uniform. After the web travels through the production line’s calender section, the strip-off, or pick-off roll, strips the sheet from the calendering rolls.

To impart the film’s surface finish, the sheet goes through an embossing unit. Here, the film is pressed onto an embossing cylinder with a matte-rubber pressure cylinder. The resultant surface finish depends upon this embossing cylinder’s condition. A high-gloss surface is achieved from a highly polished chrome cylinder, whereas a matte surface is achieved from a matte-engraved emboss cylinder. The film’s reverse side has an unspecified matte surface. 

After the sheet is calendered, it is passed through a series of rollers, which impart a surface finish.  In this manufacturing stage, the thickness of the sheet is measured continually across the web to ensure product consistency. Photo courtesy of Achilles USA, Inc.

As the vinyl sheet passes over and under a series of chilling rolls in the cooling section, the vinyl quickly cools. The cooling process anneals the vinyl into its final form.

The vinyl film is then wound, using highly sophisticated, progressive-tension winders, to minimize any tension that could result in future, dimensional-stability issues. For high-gloss films with a soft hand, it’s important to keep roll lengths to a minimum, with controlled winding tension, to reduce the tendency for gloss reduction through the roll. This reduction is caused by “cold embossing” — the matte reverse side presses onto the roll’s high-gloss surface. This is temporary “damage,” and the gloss can easily be refreshed with heat during subsequent processing.

After the film is wound into a master roll, it is shipped to an adhesive coater, such as RTape. Photo courtesy of Achilles USA, Inc.
Although the facestock is a vinyl film’s key ingredient, it’s only one ingredient in the pressure-sensitive sandwich. How a film cuts, weeds and handles depends on how all the components work together. Two rolls of the same facestock, coated with different adhesives, will likely perform differently. Remember this why it is important that you evaluate each new vinyl film product.

RECOMMENDED VINYL GRAPHICS APPLICATION TOOLS


SEALITPEN

● Felt tipped marker filled with acrylic clear coat. 
● Use the SEALITPEN to edge seal a vinyl graphic. 
● A clean way to apply edge sealer - no brush required. 



3M Brand 3950 Edge Sealer


● Seals exposed edges of vinyl graphics.

● Prevents pressure-sensitive vinyl films from lifting resulting from environmental exposure or cleaning.

● Easy to apply clear edge sealer with a small artist’s paint brush or sign maker’s quill.

● Essential sealer for any professional graphics installer.

● Suitable for graphics applications in temperatures from 50°F to 100°F.



3M Tape Primer 94 1/2 Pint 8oz For Vinyl

● Promotes adhesion of all brands of pressure sensitive vinyl films and 3M™ VHB™ Tape.
● Use when vinyl graphics will be stretched into concave areas.
● Use complex vehicle contours, such as bumpers.
● For use on difficult to stick to and low energy surfaces such polyethylene, polypropylene, ABS, PET/PBT blends, concrete, wood, glass, metal and painted metal surfaces.
● Dries to a clear finish.
● Cleans up with isopropyl alcohol.




Steinel HG 2510 ESD Programmable IntelliTemp Heat Gun with a LDC Display 


● Temperature range: 120°F - 1200°F.
● LCD display enables temperature selection in 10°F increments
● Ideal for applications requiring precision control.




Visit My Vinyl Sign Techniques Community

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Vinyl Application Videos

Squeegee Technique. Nothing is more basic in vinyl application than the squeegee. But some squeegees work better than others. And there are right ways and wrong ways to use this simple tool. This video clip reviews squeegee selection, squeegee care and squeegee technique. Click to Link

Wet Applications. Dry applications are typically recommended for most vinyl applications. For those exceptions to the rule, this instructional video explains the right way to perform a wet application. Click to Link

Application of Window Graphics. Installing vinyl graphics on glass can be challenging, because the adhesive aggressively grabs onto this high energy surface. Repositioning graphics on window is generally difficult, if not impossible. This instructional video explains how to dry apply window graphics right the first time. It also describes the necessary steps required for surface preparation. Click to Link

Transferring Frosted Window Graphics Films.  Because frosted window films are highly textured, transferring cut vinyl graphics can be problematic. This video provides direction in selection of the right application tape and how to apply these films quickly, easily and without problems. Click to Link

3-Step Surface Prep. This instructional video describes how to properly clean the surface of a vehicle before applying pressure sensitive vinyl graphics to a trailer or doing a full wrap of a car or van. This three step surface prep involves detergent washing, solvent cleaning and a final wipe down with IPA. Click to Link


Vinyl Application Over Rivets. Applying vinyl graphics on vehicle surfaces with rivets is challenging for most sign makers. Vinyl failures to these surfaces are all too common. This video demonstrates some tips and procedures, used by professional decal installers, which will make these demanding applications easier and more trouble-free.  Click to Link

Vinyl Application to Corrugations. Learn how to apply vinyl graphics to corrugations in a relaxed state. Forcing films into the valleys of corrugations puts too much mechanical stress on the film. Sooner or later, the vinyl will lift or tent in valleys. Click to Link

Applying Air Egress Vinyls. Vinyl films with air egress release liners have almost eliminated bubbles and wrinkles from applied graphics. Air egress release liners with their highly textured surface structure are problematic. Not much will stick to these liners other than the vinyl film. At RTape our best premask solution for air egress liners is a special Conform® tape called 4761RLA. Click to Link


About Jim Hingst: After fourteen years as Business Development Manager at RTape, Jim Hingst retired. He was involved in many facets of the company’s business, including marketing, sales, product development and technical service.

Hingst began his career 42 years ago in the graphic arts field creating and producing advertising and promotional materials for a large test equipment manufacturer.  Working for offset printers, large format screen printers, vinyl film manufacturers, and application tape companies, his experience included estimating, production planning, purchasing and production art, as well as sales and marketing. In his capacity as a salesman, Hingst was recognized with numerous sales achievement awards.

Drawing on his experience in production and as graphics installation subcontractor, Hingst provided the industry with practical advice, publishing more than 150 articles for  publications, such as  Signs Canada, SignCraft,  Signs of the Times, Screen Printing, Sign and Digital Graphics and  Sign Builder Illustrated. He also posted more than 325 stories on his blog (hingstssignpost.blogspot.com). In 2007 Hingst’s book, Vinyl Sign Techniques, was published.  Vinyl Sign Techniques is available at sign supply distributors and at Amazon. 
© 2016 Jim Hingst

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